2019
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In situ iron coating on nanocatalysts for efficient and durable oxygen evolution reaction
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Abstract
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“…That is, the Co/Ni-CW catalyst requires the lowest overpotential of 330 mV to achieve 10 mA cm -2 , and a large current density of 68.5 mA cm -2 at 410 mV, demonstrating the large current densities at small cell voltage for overall water splitting. Additionally, the Co/Ni-CW with a low overpotential at the current density of 10 mA cm -2 can also be competitive against those of representative Ni and Co-based electrocatalysts, [25][26][27][28][29][35][36][37][38] suggesting the effective activity of Co/Ni-CW toward OER (Figure 4b).…”
Section: Results
mentioning
confidence: 99%
“…b) Comparisons of overpotentials at a current density of 10 mA cm –2 for Co/Ni‐CW with other OER catalysts. [ 25–29,35–38 ] c) Tafel plots of Co/Ni‐CW, Co‐CW, and Ni‐CW derived from (a). d) Polarization curves for HER on Co/Ni‐CW, Co‐CW, and Ni‐CW by normalizing to the ECSA.…”
Section: Results
mentioning
confidence: 99%
Abstract
Smart CitationsHow this paper cites the one you are viewing
“…That is, the Co/Ni-CW catalyst requires the lowest overpotential of 330 mV to achieve 10 mA cm -2 , and a large current density of 68.5 mA cm -2 at 410 mV, demonstrating the large current densities at small cell voltage for overall water splitting. Additionally, the Co/Ni-CW with a low overpotential at the current density of 10 mA cm -2 can also be competitive against those of representative Ni and Co-based electrocatalysts, [25][26][27][28][29][35][36][37][38] suggesting the effective activity of Co/Ni-CW toward OER (Figure 4b).…”
Section: Results
mentioning
confidence: 99%
“…b) Comparisons of overpotentials at a current density of 10 mA cm –2 for Co/Ni‐CW with other OER catalysts. [ 25–29,35–38 ] c) Tafel plots of Co/Ni‐CW, Co‐CW, and Ni‐CW derived from (a). d) Polarization curves for HER on Co/Ni‐CW, Co‐CW, and Ni‐CW by normalizing to the ECSA.…”
Section: Results
mentioning
confidence: 99%
Abstract
Smart CitationsHow this paper cites the one you are viewing
“…Characterization methods, including CV, HAADF-STEM, EDS, XPS, and Raman spectroscopy, corroborated that Joule heating directly formed a multimetallic phosphate with an amorphous structure and promoted the preoxidation of active cation species, facilitating surface reconstruction and oxyhydroxide formation during electrolysis. This transient thermal processing approach can be readily adapted to create amorphous structures of various functional materials, including metal alloys, 35,38 oxides, 15,73,74 nitrides, [75][76][77] suldes, 78,79 and other phosphorous-based structures on alternative 2D substrates, [79][80][81][82] presenting signicant potential for advanced energy storage and conversion applications.…”
Section: Discussion
mentioning
confidence: 99%
Abstract
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“…Inset: LSV curves at initial and after 3000 CV cycles of Fe 2 P/CoMoP@CFC catalyst. h) Comparisons of overpotentials at a current density of 10 mA cm −2 for Fe 2 P/CoMoP@CFC with other reported OER catalysts 2,10,11,26,27,[29][30][31][32][33]. i) Similar comparison for HER catalysts 29,[33][34][35][36][37][38].…”
mentioning
confidence: 95%
“…h) Comparisons of overpotentials at a current density of 10 mA cm −2 for Fe 2 P/CoMoP@CFC with other reported OER catalysts. 2,10,11,26,27,[29][30][31][32][33] i) Similar comparison for HER catalysts. 29,[33][34][35][36][37][38] Catalysis Science & Technology Paper electrocatalysts reported in the literature (Fig.…”
Section: Catalysis Science and Technology
mentioning
confidence: 99%
Abstract
Smart CitationsHow this paper cites the one you are viewing
“…That is, the Co/Ni-CW catalyst requires the lowest overpotential of 330 mV to achieve 10 mA cm -2 , and a large current density of 68.5 mA cm -2 at 410 mV, demonstrating the large current densities at small cell voltage for overall water splitting. Additionally, the Co/Ni-CW with a low overpotential at the current density of 10 mA cm -2 can also be competitive against those of representative Ni and Co-based electrocatalysts, [25][26][27][28][29][35][36][37][38] suggesting the effective activity of Co/Ni-CW toward OER (Figure 4b).…”
Section: Results
mentioning
confidence: 99%
“…b) Comparisons of overpotentials at a current density of 10 mA cm –2 for Co/Ni‐CW with other OER catalysts. [ 25–29,35–38 ] c) Tafel plots of Co/Ni‐CW, Co‐CW, and Ni‐CW derived from (a). d) Polarization curves for HER on Co/Ni‐CW, Co‐CW, and Ni‐CW by normalizing to the ECSA.…”
Section: Results
mentioning
confidence: 99%
Abstract
Smart CitationsHow this paper cites the one you are viewing
“…Characterization methods, including CV, HAADF-STEM, EDS, XPS, and Raman spectroscopy, corroborated that Joule heating directly formed a multimetallic phosphate with an amorphous structure and promoted the preoxidation of active cation species, facilitating surface reconstruction and oxyhydroxide formation during electrolysis. This transient thermal processing approach can be readily adapted to create amorphous structures of various functional materials, including metal alloys, 35,38 oxides, 15,73,74 nitrides, [75][76][77] suldes, 78,79 and other phosphorous-based structures on alternative 2D substrates, [79][80][81][82] presenting signicant potential for advanced energy storage and conversion applications.…”
Section: Discussion
mentioning
confidence: 99%
Abstract
Smart CitationsHow this paper cites the one you are viewing
“…Inset: LSV curves at initial and after 3000 CV cycles of Fe 2 P/CoMoP@CFC catalyst. h) Comparisons of overpotentials at a current density of 10 mA cm −2 for Fe 2 P/CoMoP@CFC with other reported OER catalysts 2,10,11,26,27,[29][30][31][32][33]. i) Similar comparison for HER catalysts 29,[33][34][35][36][37][38].…”
mentioning
confidence: 95%
“…h) Comparisons of overpotentials at a current density of 10 mA cm −2 for Fe 2 P/CoMoP@CFC with other reported OER catalysts. 2,10,11,26,27,[29][30][31][32][33] i) Similar comparison for HER catalysts. 29,[33][34][35][36][37][38] Catalysis Science & Technology Paper electrocatalysts reported in the literature (Fig.…”
Section: Catalysis Science and Technology
mentioning
confidence: 99%
Abstract
Smart CitationsHow this paper cites the one you are viewing
“…That is, the Co/Ni-CW catalyst requires the lowest overpotential of 330 mV to achieve 10 mA cm -2 , and a large current density of 68.5 mA cm -2 at 410 mV, demonstrating the large current densities at small cell voltage for overall water splitting. Additionally, the Co/Ni-CW with a low overpotential at the current density of 10 mA cm -2 can also be competitive against those of representative Ni and Co-based electrocatalysts, [25][26][27][28][29][35][36][37][38] suggesting the effective activity of Co/Ni-CW toward OER (Figure 4b).…”
Section: Results
mentioning
confidence: 99%
“…b) Comparisons of overpotentials at a current density of 10 mA cm –2 for Co/Ni‐CW with other OER catalysts. [ 25–29,35–38 ] c) Tafel plots of Co/Ni‐CW, Co‐CW, and Ni‐CW derived from (a). d) Polarization curves for HER on Co/Ni‐CW, Co‐CW, and Ni‐CW by normalizing to the ECSA.…”
Section: Results
mentioning
confidence: 99%
Abstract
Smart CitationsHow this paper cites the one you are viewing
“…Characterization methods, including CV, HAADF-STEM, EDS, XPS, and Raman spectroscopy, corroborated that Joule heating directly formed a multimetallic phosphate with an amorphous structure and promoted the preoxidation of active cation species, facilitating surface reconstruction and oxyhydroxide formation during electrolysis. This transient thermal processing approach can be readily adapted to create amorphous structures of various functional materials, including metal alloys, 35,38 oxides, 15,73,74 nitrides, [75][76][77] suldes, 78,79 and other phosphorous-based structures on alternative 2D substrates, [79][80][81][82] presenting signicant potential for advanced energy storage and conversion applications.…”
Section: Discussion
mentioning
confidence: 99%
Abstract
Smart CitationsHow this paper cites the one you are viewing
“…Inset: LSV curves at initial and after 3000 CV cycles of Fe 2 P/CoMoP@CFC catalyst. h) Comparisons of overpotentials at a current density of 10 mA cm −2 for Fe 2 P/CoMoP@CFC with other reported OER catalysts 2,10,11,26,27,[29][30][31][32][33]. i) Similar comparison for HER catalysts 29,[33][34][35][36][37][38].…”
mentioning
confidence: 95%
“…h) Comparisons of overpotentials at a current density of 10 mA cm −2 for Fe 2 P/CoMoP@CFC with other reported OER catalysts. 2,10,11,26,27,[29][30][31][32][33] i) Similar comparison for HER catalysts. 29,[33][34][35][36][37][38] Catalysis Science & Technology Paper electrocatalysts reported in the literature (Fig.…”
Section: Catalysis Science and Technology
mentioning
confidence: 99%