1997
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Abstract: A combination of electrospray ionization MS/MS techniques, isotopic labeling experiments in the gas-phase and solution, and ab initio calculations is used to study the C−H activation reactions of [Cp*Ir(PMe3)(CH3)]+ and [CpIr(PMe3)(CH3)]+. The reaction in the gas phase was found to proceed through a Cp or [Cp*Ir(η2-CH2PMe2)]+ intermediate. Quantitative collision-induced dissociation (CID) threshold measurements were used along with general models for ion−molecule reactions to construct potential energy diagram… Show more

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