1998
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Abstract: The dynamics of the xanthyl radical in a series of alkali-metal cation exchanged (Li+, Na+, K+, Rb+, and Cs+) Y faujasites in the absence and presence of molecular oxygen are examined by using laser flash photolysis. Upon laser photolysis of xanthene-9-carboxylate incorporated within the supercages of NaY in the absence of oxygen, prompt formation of the xanthyl radical and the xanthylium cation is observed. The xanthyl radical is formed by photoionization of xanthene-9-carboxylate to the corresponding acyloxy… Show more

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