2021
DOI: 10.1021/acs.macromol.0c02526 View full text |Buy / Rent full text
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Abstract: Polyelectrolyte brushes have received extensive attention due to their swelling behavior in aqueous solutions, which is a result of their ionic nature and nonelectrostatic (polymer–polymer and polymer–solvent) interactions. While the nonelectrostatic contributions are typically assumed to be negligible compared to the ion osmotic pressure, we present herein a systematic investigation of how the nonelectrostatic interactions dramatically affect the swelling behavior of polyelectrolyte brushes. Using a modular s… Show more

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