1997
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Abstract: A study of the redox behavior of the cobalt complex of octaethylbilindione (H3OEB), a biliverdin analog, reveals that coordination of the ligand allows its complexes to undergo reversible, one-electron transfer processes, whereas the free ligand itself undergoes an irreversible two-electron oxidation. Thus, the four-membered electron transfer series involving [Co(OEB)] n with n = +1, 0, −1, −2 has been observed electrochemically. The most highly oxidized member of this series has been isolated… Show more

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