1997
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Abstract: The structural characteristics and reactivity of the gas-phase FSi(OCH3)2(OCH2)- ion were investigated by a combination of ab initio calculations and FT-ICR techniques. The theoretical calculations for different possible structures reveal that carbanion and alkoxide ion type structures lead to ring closure upon geometry optimization to yield two different cyclic fluoride−siloxirane structures. The FSi(OCH3)2(cyc-OCH2)- ions containing the elusive siloxirane ring are estimated to be extremely stable with respec… Show more

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