1997
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Abstract: The first chalcogen-bridged [1]ferrocenophanes Fe(η-C5H3R)2E (6, E = S, R = H; 7, E = Se, R = H; 12, E = S, R = Me) have been synthesized and characterized both structurally and spectroscopically. Synthesis of sulfur- and selenium-bridged species 6 and 7 was achieved by the reaction of dilithioferrocene·TMEDA (TMEDA = tetramethylethylenediamine) with bis(phenylsulfonyl) sulfide S(O2SPh)2 and selenium diethyldithiocarbamate Se(S2CNEt2)2, respectively, in 20−30% yields. Structural characterization of both 6 and … Show more

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