1997
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Abstract: Black Pt effected the hydrogenation of Ru(COD)(η 3 -C 3 H 5 ) 2 (1; COD is 1,5-cyclooctadiene) by dihydrogen gas (pressure ∼1 atm) at -10°C in hexanes. The hydrogenation resulted in adsorption of Ru adatoms by the surface of Pt with concomitant formation of propane, cyclooctane, and small amounts of cis-bicyclo[3.3.0]octane and n-octane. Compound 1 did not react with dihydrogen gas under these conditions in the absence of Pt. The total amount of cyclooctane, bicyclo[3.3.0]octane, and n-octane in solution was e… Show more

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