2021
DOI: 10.1021/jacs.1c00189 View full text |Buy / Rent full text
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Abstract: Octaaryl-substituted bisquinodimethanes (BQDs) with a zigzag structure were designed as redox switchable molecules that undergo four-electron oxidation to produce tetracationic pentacenes with a doubly twisted structure. In contrast to one-stage four-electron oxidation of BQDs, stepwise two-electron reduction of tetracationic pentacenes occurs to give dicationic anthracenes and then the original BQDs, step-by-step. Since both tetra-/dications exhibit near-infrared (NIR) absorptions (-1,400 nm) based on an intr… Show more

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