1997
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Abstract: Kinetic measurements as well as B3LYP/ and MP2/6-31G(d,p) calculations provide evidence that carbonyl oxides formed in the gas-phase ozonolysis of alkylated alkenes are an important source of OH radicals. In the gas-phase ozonolysis of propene, cis-2-butene, trans-2-butene, tetramethylethene, and isoprene, 18, 17, 24, 36, and 19% OH radicals (relative to reacted ozone, error margin ≤4%) are measured using CO as a scavenger for OH. The quantum chemical calculations show that OH radical production depends on syn… Show more

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