1993
DOI: 10.1021/ic00078a027 View full text |Buy / Rent full text
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Abstract: Beer's law plots for the oxo-bridged d'-d* 1 dimers [ 2 3{$2 ( )2}4] (R = Et, 3; R = Ph, 4; R = Me, 5) exhibit positive deviations from linearity, suggestive of dissociative equilibria. In the case of 3 it has been established by 31P NMR that this is a consequence of the disproportionation equilibrium between 3 and its d2 and d°d isproportionation products [MoO{S2P(OEt)2}2] ( 6) and [Mo02{S2P(OEt)2}2] (7), both of which have been independently prepared.3 'P NMR spectroscopy has been used to measure the dissoc… Show more

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