1996
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Abstract: The rate constants and the yields of the products of the nucleophilic substitution and elimination reactions of 1-(4-methoxyphenyl)-3-methyl-3-butyl derivatives (1-X) have been determined in mostly aqueous solvents, and the absolute rate constant for reaction of the simple tertiary carbocation 1 + in 50:50 (v/v) trifluoroethanol/water has been estimated as k s = 3.5 × 1012 s-1. Product studies show that the acid-catalyzed reactions of 1-OH and 4-(4-methoxyphenyl)-2-methyl-1-butene (2) do not … Show more

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