1996
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Abstract: A description of the structure and bonding of novel bis(μ-oxo)dicopper complexes and their bis(μ-hydroxo)dicopper decomposition products was derived from combined X-ray crystallographic, spectroscopic, and ab initio theoretical studies. The compounds [(LCu)2(μ-O)2]X2 were generated from the reaction of solutions of [LCu(CH3CN)]X with O2 at −80 °C (L = 1,4,7-tribenzyl-1,4,7-triazacyclononane, LBn 3 ; 1,4,7-triisopropyl-1,4,7-triazacyclononane, LiPr 3 ; or 1-benzyl-4,7-diisopropyl-1,4,7-triazacyclononane, LiPr… Show more

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