Structure-Activity Relationships Over Ru-Based Catalysts in Anisole Demethoxylation: Spectroscopic and Kinetic Studies

Boosting Photocatalytic Conversion of Glucose by Constructing Oxygen Vacancies in TiO2‐x

“…In the 2200–2000 cm –1 region, characteristic CO bands were detected [96–98]. Moreover, both CO characteristic bands exhibited a rapid increase followed by a decrease with time (Supporting Information S1: Figure ), indicating that CO is an intermediate product in the reaction process.…”

“…Under the oxygen atmosphere, the CO adsorption bands appeared in the range of 2140–2040 cm –1 . This suggests that, on the modified titanium dioxide catalyst HRT‐500, CO forms a complex with the metal, resulting in C≡O stretching vibrations appearing in the 2100–2000 cm –1 range [98].…”

Boosting Photocatalytic Conversion of Glucose by Constructing Oxygen Vacancies in TiO2‐x

“…In the 2200–2000 cm –1 region, characteristic CO bands were detected [96–98]. Moreover, both CO characteristic bands exhibited a rapid increase followed by a decrease with time (Supporting Information S1: Figure ), indicating that CO is an intermediate product in the reaction process.…”

“…Under the oxygen atmosphere, the CO adsorption bands appeared in the range of 2140–2040 cm –1 . This suggests that, on the modified titanium dioxide catalyst HRT‐500, CO forms a complex with the metal, resulting in C≡O stretching vibrations appearing in the 2100–2000 cm –1 range [98].…”

Aqueous phase reforming of glycerol over Pt/NiAl2O4 catalyst

“…Ni-based catalysts. 13,[27][28][29][30][31][32][33][34] Among these, Pt has received the most attention due to its high activity and H 2 selectivity. 21 Besides, for loaded catalysts, both the metal and the support have important effects on their activity.…”

“…It has been reported that the doping of nickel oxide could promote the stability of alumina. 32,[41][42][43] NiAl 2 O 4 with an inverted spinel structure has been shown to exhibit favorable thermal stability due to its formation at elevated temperatures. Moreover, NiAl 2 O 4 maintains high thermal stability in methane combustion even in the presence of water.…”

“…To obtain hydrogen, the catalyst for APR must demonstrate high catalytic activity for C–C and C–H bond cleavage and water‐gas shift (WGS) reactions, while inhibiting C–O bond cleavage 20 . At present, most of the research in this field is focused on Pt‐, Pd‐, Ir‐, Rh‐, Ru‐, Co‐, and Ni‐based catalysts 13,27–34 . Among these, Pt has received the most attention due to its high activity and H 2 selectivity 21 .…”

Boosting Photocatalytic Conversion of Glucose by Constructing Oxygen Vacancies in TiO2‐x

“…In the 2200–2000 cm –1 region, characteristic CO bands were detected [96–98]. Moreover, both CO characteristic bands exhibited a rapid increase followed by a decrease with time (Supporting Information S1: Figure ), indicating that CO is an intermediate product in the reaction process.…”

“…Under the oxygen atmosphere, the CO adsorption bands appeared in the range of 2140–2040 cm –1 . This suggests that, on the modified titanium dioxide catalyst HRT‐500, CO forms a complex with the metal, resulting in C≡O stretching vibrations appearing in the 2100–2000 cm –1 range [98].…”

Aqueous phase reforming of glycerol over Pt/NiAl2O4 catalyst

“…Ni-based catalysts. 13,[27][28][29][30][31][32][33][34] Among these, Pt has received the most attention due to its high activity and H 2 selectivity. 21 Besides, for loaded catalysts, both the metal and the support have important effects on their activity.…”

“…It has been reported that the doping of nickel oxide could promote the stability of alumina. 32,[41][42][43] NiAl 2 O 4 with an inverted spinel structure has been shown to exhibit favorable thermal stability due to its formation at elevated temperatures. Moreover, NiAl 2 O 4 maintains high thermal stability in methane combustion even in the presence of water.…”

“…To obtain hydrogen, the catalyst for APR must demonstrate high catalytic activity for C–C and C–H bond cleavage and water‐gas shift (WGS) reactions, while inhibiting C–O bond cleavage 20 . At present, most of the research in this field is focused on Pt‐, Pd‐, Ir‐, Rh‐, Ru‐, Co‐, and Ni‐based catalysts 13,27–34 . Among these, Pt has received the most attention due to its high activity and H 2 selectivity 21 .…”

Boosting Photocatalytic Conversion of Glucose by Constructing Oxygen Vacancies in TiO2‐x

“…In the 2200–2000 cm –1 region, characteristic CO bands were detected [96–98]. Moreover, both CO characteristic bands exhibited a rapid increase followed by a decrease with time (Supporting Information S1: Figure ), indicating that CO is an intermediate product in the reaction process.…”

“…Under the oxygen atmosphere, the CO adsorption bands appeared in the range of 2140–2040 cm –1 . This suggests that, on the modified titanium dioxide catalyst HRT‐500, CO forms a complex with the metal, resulting in C≡O stretching vibrations appearing in the 2100–2000 cm –1 range [98].…”

Aqueous phase reforming of glycerol over Pt/NiAl2O4 catalyst

“…Ni-based catalysts. 13,[27][28][29][30][31][32][33][34] Among these, Pt has received the most attention due to its high activity and H 2 selectivity. 21 Besides, for loaded catalysts, both the metal and the support have important effects on their activity.…”

“…It has been reported that the doping of nickel oxide could promote the stability of alumina. 32,[41][42][43] NiAl 2 O 4 with an inverted spinel structure has been shown to exhibit favorable thermal stability due to its formation at elevated temperatures. Moreover, NiAl 2 O 4 maintains high thermal stability in methane combustion even in the presence of water.…”

“…To obtain hydrogen, the catalyst for APR must demonstrate high catalytic activity for C–C and C–H bond cleavage and water‐gas shift (WGS) reactions, while inhibiting C–O bond cleavage 20 . At present, most of the research in this field is focused on Pt‐, Pd‐, Ir‐, Rh‐, Ru‐, Co‐, and Ni‐based catalysts 13,27–34 . Among these, Pt has received the most attention due to its high activity and H 2 selectivity 21 .…”