A transparent and stretchable all-graphene multifunctional electronic-skin sensor matrix is developed. Three different functional sensors are included in this matrix: humidity, thermal, and pressure sensors. These are judiciously integrated into a layer-by-layer geometry through a simple lamination process.
We report the facile fabrication of a functional nanoporous multilayer film with wettability that is reversibly tunable between superhydrophobicity and superhydrophilicity with UV/visible irradiation. Our approach controls surface roughness with an electrostatic self-assembly process and makes use of the photoresponsive molecular switching of fluorinated azobenzene molecules. Selective UV irradiation onto the nanostructured substrate was used to realize substrates with erasable and rewritable patterns of extreme wetting properties. Our findings will open up new avenues for external stimuli-responsive smart surfaces.
Human skin imperfectly discriminates between pressure and temperature stimuli under mixed stimulation, and exhibits nonlinear sensitivity to each stimulus. Despite great advances in the field of electronic skin (E-skin), the limitations of human skin have not previously been overcome. For the first time, the development of a stimulus-discriminating and linearly sensitive bimodal E-skin that can simultaneously detect and discriminate pressure and temperature stimuli in real time is reported. By introducing a novel device design and using a temperature-independent material, near-perfect stimulus discriminability is realized. In addition, the hierarchical contact behavior of the surface-wrinkled microstructure and the optimally reduced graphene oxide in the E-skin contribute to linear sensitivity to applied pressure/temperature stimuli over wide intensity range. The E-skin exhibits a linear and high pressure sensitivity of 0.7 kPa up to 25 kPa. Its operation is also robust and exhibits fast response to pressure stimulus within 50 ms. In the case of temperature stimulus, the E-skin shows a linear and reproducible temperature coefficient of resistance of 0.83% K in the temperature range 22-70 °C and fast response to temperature change within 100 ms. In addition, two types of stimuli are simultaneously detected and discriminated in real time by only impedance measurements.
Obtaining control over the supramolecular organization of electronically active p-conjugated polymers [1] would make it possible to fine-tune and optimize their electrical properties for applications in organic field-effect transistors (OFETs) [2][3][4][5] and sensors. [6,7] Typically, it is far more challenging to obtain high-quality single crystals of conjugated polymers by facile solution processing than oligomers [8] and small molecules, [9] which are prepared by vacuum processes. However, 1D, highquality, single-crystal semiconductors comparable to inorganic single crystals, such as silicon nanowires, have not hitherto been observed for conjugated polymers. Self-organized poly(3-hexylthiophene) (P3HT), [10][11][12][13][14][15][16][17][18] with its supramolecular 2D structure, is of special interest because the 1D electronic properties of the p-conjugated polymer chains are modified by the increased interchain stacking that results from p-p interactions. Therefore, the possibility of achieving good electrical performance as a result of 2D transport (i.e., band-like transport) in self-organized single-crystal P3HT has spurred its use in enhanced polymer electronic devices (PEDs). By better control of structural anisotropy, and by developing P3HT structures with strongly p-p interacting building blocks coinciding with the direction of current flow in PEDs, optimized electrical performance and, possibly, a truly delocalized transport regime may be attained. We report here the preparation and properties of high-quality, 1D single-crystal P3HT microwires grown by a facile self-assembly process in dilute solution. Figure 1 outlines the fabrication steps for the preparation of low-voltage, gate-modulated PEDs based on well-faceted, 1D single-crystal P3HT microwires. Dense octadecyltrichlorosilane (ODTS) self-assembled monolayers (SAMs) (structure shown in Fig. 1A) possessing sufficient robustness are used as the molecular dielectrics to reduce the operating voltage of COMMUNICATIONS
The creation of an artificial superhydrophobic surface with micro- and nanostructures has been demonstrated using a block copolymer micelle solution and silica nanoparticles. The unique technique of a nanoparticle-supported micelle stabilization together with changes in the solvent power guarantees the precise morphology control of certain block copolymer-mediated surfaces. The approaches presented here provide a new strategy for the fabrication of a wettability-controlled organic-inorganic hybrid or organic coatings.
3D printing of reduced graphene oxide (rGO) nanowires is realized at room temperature by local growth of GO at the meniscus formed at a micropipette tip followed by reduction of GO by thermal or chemical treatment. 3D rGO nanowires with diverse and complicated forms are successfully printed, demonstrating their ability to grow in any direction and at the selected sites.
Large-area amorphous calcium carbonate (ACC) films in air are shown to be transformed into crystalline calcium carbonate (CaCO(3)) films via two modes-dissolution-recrystallization and solid-solid phase transition-depending on the relative humidity of the air and the temperature. Moisture in the air promotes the transformation of ACC into crystalline forms via a dissolution-recrystallization process. Increasing the humidity increases the rate of ACC crystallization and gives rise to films with numerous large pores. As the temperature is increased, the effect of moisture in the air is reduced and solid-solid transition by thermal activation becomes the dominant transformation mechanism. At 100 and 120 degrees C, ACC films are transformed into predominantly (110) oriented crystalline films. Collectively, the results show that calcium carbonate films with different morphologies, crystal phases, and structures can be obtained by controlling the humidity and temperature. This ability to control the transformation of ACC should assist in clarifying the role of ACC in the biomineralization of CaCO(3) and should open new avenues for preparing CaCO(3) films with oriented and fine structure.
A supramolecular organosilane, 2-(3-(triethoxysilyl)propylaminocarbonylamino)-6-methyl-4[1H]pyrimidinone comprising quadruple hydrogen bonds has been synthesized in one step from commercially available starting materials. The synthesized supramolecular organosilane can be stabilized and phase-separated by dimerization via the linear array of quadruple hydrogen bonds in solution. This property of the supramolecular organosilane has been exploited to fabricate structuring materials having a superhydrophobic surface property. We have successfully generated the interconnected granular structure with adequate roughness for superhydrophobicity via sol-gel process.
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