No abstract

No abstract

No abstract

Siloxanes are used in a wide variety of personal-care and other consumer products. Although there is clearly a potential for contamination of indoor dust with siloxanes, reports of occurrence of siloxanes in indoor dust were not available, prior to the present study. Here, we have determined the concentrations and profiles of four cyclic siloxanes, octamethylcyclotetrasiloxane (D(4)), decamethylcyclopentasiloxane (D(5)), dodecamethylcyclohexasiloxane (D(6)), and tetradecamethylcycloheptasiloxane (D(7)), as well as 11 linear siloxanes, from L(4)-L(14), in 100 dust samples collected in China. Cyclic and linear siloxanes were found in all dust samples, with the linear siloxanes L(9)-L(14) being the predominant compounds. Concentrations of total siloxanes in dust ranged from 21.5 to 21,000 (mean: 1540 +/- 2850) ng g(-1). The highest concentration of the individual linear siloxanes, L(9)-L(14), ranged between 2680 and 6170 ng g(-1). Concentrations of total linear siloxanes (TLS) were 1-2 orders of magnitude higher than concentrations of total cyclic siloxanes (TCS), in all indoor dust samples. Siloxane concentrations in dust were associated with the number of electrical/electronic appliances, number of occupants, and smokers living in the house. Based on the measured siloxane concentrations and on estimated daily ingestion rates of dust by toddlers and adults, we calculated the daily intake of siloxanes. For adults, daily exposure to total siloxanes, based on an average dust intake rate and median exposure concentration, was calculated to be 15.9 ng day(-1); the corresponding value for toddlers was 32.8 ng d(-1).

No abstract

Synthetic musk compounds are used in a wide range of personal care and other consumer products. Despite this fact, few studies have reported the occurrence of synthetic musks in house dust or exposure of humans through the ingestion of indoor dust. In the present study, we determined the concentrations and profiles of two polycyclic musks (PCMs; Galaxolide(®) [HHCB] and Tonalide(®)), three nitro musks (NMs; musk ketone [MK], musk moskene [MM], and musk xylene [MX]), and one metabolite of HHCB (HHCB-lactone), in 88 indoor-dust samples from homes, dormitories, offices, and laboratories in China. In addition, we analyzed 12 dust samples collected from inside the housings of electrical/electronic devices that were located in 10 of the houses. Synthetic musks were detected in all of the dust samples analyzed, with total concentrations (sum of PCM and NM concentrations) varying from 4.42 to 688 ng g⁻¹ (mean ± SD: 126 ± 16.2 ng g⁻¹; median: 82.7 ng g⁻¹). HHCB was the predominant compound in all of the dust samples analyzed accounting on average for 42.2% of the total musk concentrations. Concentrations of synthetic musks in dust samples from homes and offices were higher than the concentrations found in samples from dormitories and laboratories. Concentrations of synthetic musks in dust samples increased with the increasing number of occupants in homes. Based on the concentrations, levels of exposure to musks by way of dust ingestion were calculated to be up to 25.8 ng d⁻¹ for adults and 138 ng d⁻¹ for toddlers.

No abstract

As a promising cathode material for lithium‐ion batteries, nitrogen‐rich LiNi0.8Co0.1Mn0.1O2 (NCM811) attracts great attention for its high specific capacity, but the rapid capacity decline of NCM811 in the process of charge/discharge restricts its extensive application. To alleviate the capacity decline for NCM811, a solid electrolyte LiNbO3 material with lithium‐ion diffusion and electron conduction activity was successfully coated on the surface of NCM811 by adopting a simple two‐step method, and the amount of the LiNbO3 coating layer was investigated. Powder X‐ray diffraction, scanning electron microscopy, transmission electron microscopy, and X‐ray photoelectron spectroscopy were used to characterize the as‐prepared cathode materials. The experimental results revealed that the LiNbO3 played a role in reducing surface residual alkalis and protecting NCM811 from erosion by electrolyte. When the weight ratio of LiNbO3 and NCM811 was 1 %, the corresponding 1 wt % LNO@NCM material displayed the best cycle performance and rate capability, whose capacity retention at 1 C after 200 cycles, and discharge capacity at 10 C are 90.1 % and 122.7 mAh g−1, respectively.