Quantum key distribution (QKD) 1,2 provides the only intrinsically unconditional secure method for communication based on principle of quantum mechanics. Compared with fiber-based demonstrations 3-5 , free-space links could provide the most appealing solution for much larger distance. Despite of significant efforts 6-13 , so far all realizations rely on stationary sites. Justifications are therefore extremely crucial for applications via a typical Low Earth Orbit Satellite (LEOS). To achieve direct and full-scale verifications, we demonstrate here three independent experiments with a decoy-state QKD system overcoming all the demanding conditions. The system is operated in a moving platform through a turntable, a floating platform through a hot-air balloon, and a huge loss channel, respectively, for substantiating performances under rapid motion, attitude change, vibration, random movement of satellites and in high-loss regime. The experiments cover expanded ranges for all the leading parameters of LEOS. Our results pave the way towards ground-satellite QKD and global quantum communication network.

Measurement-device-independent quantum key distribution (MDIQKD) protocol is immune to all attacks on detection and guarantees the information-theoretical security even with imperfect single-photon detectors. Recently, several proof-of-principle demonstrations of MDIQKD have been achieved. Those experiments, although novel, are implemented through limited distance with a key rate less than 0.1  bit/s. Here, by developing a 75 MHz clock rate fully automatic and highly stable system and superconducting nanowire single-photon detectors with detection efficiencies of more than 40%, we extend the secure transmission distance of MDIQKD to 200 km and achieve a secure key rate 3 orders of magnitude higher. These results pave the way towards a quantum network with measurement-device-independent security.

Quantum cryptography holds the promise to establish an information-theoretically secure global network. All field tests of metropolitan-scale quantum networks to date are based on trusted relays. The security critically relies on the accountability of the trusted relays, which will break down if the relay is dishonest or compromised. Here, we construct a measurement-device-independent quantum key distribution (MDIQKD) network in a star topology over a 200-square-kilometer metropolitan area, which is secure against untrustful relays and against all detection attacks. In the field test, our system continuously runs through one week with a secure key rate 10 times larger than previous results. Our results demonstrate that the MDIQKD network, combining the best of both worlds-security and practicality, constitutes an appealing solution to secure metropolitan communications.

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Quantum key distribution (QKD) utilizes the laws of quantum mechanics to achieve informationtheoretically secure key generation. This field is now approaching the stage of commercialization, but many practical QKD systems still suffer from security loopholes due to imperfect devices. In fact, practical attacks have successfully been demonstrated. Fortunately, most of them only exploit detection-side loopholes which are now closed by the recent idea of measurement-deviceindependent QKD. On the other hand, little attention is paid to the source which may still leave QKD systems insecure. In this work, we propose and demonstrate an attack that exploits a source-side loophole existing in qubit-based QKD systems using a weak coherent state source and decoy states. Specifically, by implementing a linear-optics unambiguous-state-discrimination measurement, we show that the security of a system without phase randomization -which is a step assumed in conventional security analyses but sometimes neglected in practice -can be compromised. We conclude that implementing phase randomization is essential to the security of decoy-state QKD systems under current security analyses.

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The advantages of organic–inorganic hybrid halide perovskites and related materials, such as high absorption coefficient, appropriate band gap, excellent carrier mobility, and long carrier life, provide the possibility for the preparation of low-cost and high-efficiency solar cell materials. Among the inorganic materials, CsPbI 3 is paid more attention to by researchers as CsPbI 3 has incomparable advantages. In this paper, based on density functional theory (DFT), we first analyze the crystal structure, electronic properties, and work function of two common bulk structures of CsPbI 3 and their slices, and then, we study the carrier mobility, exciton binding energy, and light absorption coefficient. Considering that CsPbI 3 contains heavy elements, the spin–orbit coupling (SOC) effect was also considered in the calculation. The highest mobility is that electrons of the cubic structure reach 1399 cm 2 V –1 S –1 after considering the SOC effect, which is equal to that of traditional solar cells (such as Si-based, PbSe, and PbTe). The lowest exciton binding energy is 101 meV in the cubic bulk structure, which is beneficial to the separation of photogenerated carriers. In the visible region, the absorption coefficient of the cubic structure is the best among all structures, reaching 10 5 cm –1 . Through the study of mobility, exciton binding energy, and light absorption coefficient, it is found that the cubic bulk structure in all structures of CsPbI 3 has the best photoelectric performance. This paper can provide some guidance for the experimental preparation of CsPbI 3 as a potential high-efficiency solar cell material.